The series takes place next week with the likes of Wolf Alice, Garbage and Manic Street Preachers performing
Rodrigo has also teased that her third album is made up of "sad love songs"
Other artists involved include Bring Me The Horizon, Sex Pistols and Nia Archives, and there will also be signed prints available
The icon caught up with NME to tell us about losing her father, why Teenage Cancer Trust is a cause close to her heart, the "dream come true" of playing with Skunk Anansie, why headline tours are a thing of the past for the band, and "the power of coming together"
Black Sabbath, Radiohead, The Cure and Johnny Cash all feature in Guy Ritchie's new series
They have teased the possibility of playing the 1985 single at their March 26 show
Two Manic Street Preachers solo records - James Dean Bradfield's 'The Great Western' and Nicky Wire's 'Intimism' - will also be available
He took home Record Of The Year for 'Luther', as well as a clean sweep of the rap categories
They won Best Alternative Music Album for their comeback record and Best Alternative Music Performance for 'Alone'
They join previously announced headliners The Cure, Lewis Capaldi, and Calvin Harris